Steve Bee, Group Marketing and Strategic Projects Director of marine fuels testing company VPS, on Tuesday (22 July) highlighted the different fuel management approaches required to avoid instability and de-stablization of marine fossil fuels and biofuels:
Today’s ships can carry a number of different marine fuel types, from High Sulphur Fuel Oils (HSFOs), to Very Low Sulphur Fuel Oils (VLSFOs), Marine Gas Oils (MGOs), Ultra Low Sulphur Fuel Oils (ULSFOs), Biofuels, LNG and Methanol. Each of these fuels have varying degrees of stability, or instability, which can be triggered by numerous causes and effects.
However, to mitigate the risks of de-stabilsation, a range of fuel management approaches can be applied to marine fuels. This paper aims to cover the more common fuels, their associated stability issues and how to monitor and potentially overcome them.
High Sulphur Fuel Oil (HSFO) & Very Low Sulphur Fuel Oil (VLSFO)
Today, residual fuel is often referred to as HSFO, whereas VLSFO is a blended fuel of mainly distillates and residual fuels, which results in a usually less stable fuel than HSFO. Yet VLSFOs are still prone to certain similar stability concerns as its 100% residual counterpart and hence the associated test parameters.
Residual fuel, is comprised of process residues where the fractions did not boil during refining. These fuels contain asphaltenes, usually between 3-10%, which are the organic part of the crude oil, or residual oil, that is not soluble in straight chain solvents, eg pentane, heptane.
Asphaltenes exist as a colloidal suspension stabilized by resin molecules (aromatic ring systems) in the oil. The stability of asphaltic dispersions depends on the ratio of resin to asphaltene molecules.
The determination of the quantity of resin is important in estimating the potential damage created by asphaltenes. Asphaltene precipitates as a result of pressure drop, temperature, acids, mixing of incompatible oils, chemical contaminants, or other conditions and/or materials that break the stability of the asphaltic dispersion. This is the sludge witnessed when marine fuels de-stabilize.
The ability to retain asphaltenes within the fuel solution is known as the “Stability Reserve” of the fuel.
Bulk residual fuel stored for long periods can become unstable, where the asphaltene content can precipitate out of solution causing the formation of sludge. This has the potential to block filters and pipes, leaving tanks with an unpumpable residue. The ‘fuel break up’ is dependent on the nature of the liquid hydrocarbons in which the asphaltenes are suspended. If the medium is aromatic then they will remain in suspension. If it’s paraffinic, the asphaltenes may have a propensity to coalesce into sludge. Once a fuel has chemically broken down there is no way to satisfactorily reverse the process. Precipitated asphaltene cannot be redissolved.
Industry best practice is to avoid mixing fuels. Arbitrary comingling can lead to incompatibility problems and a loss of stability in the resultant blend. For example, when a heavy fuel oil with a high asphaltene content is mixed with a low-gravity distillate with a predominance of paraffinic aliphatic hydrocarbons, the stability reserve can be depleted and asphaltenes can flocculate and precipitate as sludge.
Compatibility problems must be treated as a critical concern, as they can lead to fuel starvation in diesel generators, potentially resulting in power loss. Incompatibility may cause fuel system paralysis and the subsequent clean-up is often both complex and time-consuming. There is a very simple, indicative test which can be carried out to highlight a fuels compatibility, the ASTM D4740 “spot test” . Here a blend composed of representative volumes of the sample fuel and the blend stock is heated and homogenized. A drop of the blend is put on a test paper and heated to 100°C. After 1 hour, the test paper is removed from the oven and the resultant spot is examined for evidence of precipitation and rated for compatibility against D4740 reference spots.
To provide valued information regarding a residual fuel’s stability there are a series of laboratory tests to further assess stability:
Total Sediment Potential (TSP)
The measurement of sediment involves filtering the oil through a filtration medium under vacuum. The mass of sediment is reported as a percentage by mass. The test provides an indication of the stability of the fuel as asphaltenes precipitate out forming sludge, blocking filters and choking purifiers. For residual fuels, TSP involves ageing the oil at 100ºC for 24 hours. So far in 2025, 1% of all HSFO off-specifications are related to TSP, whilst 3% of all VSLFO off-specifications are related to the same parameter.
Total Sediment Accelerated (TSA): (Chemical Aging) A sample of the fuel is heated to achieve a viscosity of approximately 50Cst. After 10 minutes, a measured amount of hexadecane is added and the sample is placed in an ageing bath at 100ºC for one hour. The sample is shaken vigorously prior to passing through a filter paper. The result of the test is reported to the nearest 0.01% m/m and is expressed as Total Sediment Accelerated (TSA). The agreed limit for both TSP and TSA is 0.10% m/m. A fuel that falls below this limit should be viewed as thermally stable and able to homogenously maintain asphaltenic phase suspension.
Total Sediment Existent (TSE): A fuel sample is heated to 100ºC and passed through a filter paper. The amount of dry sludge retained on the filter paper correlates with the amount of sludge that is likely to be separated by an on-board centrifuge.
Separability Number, or Reserve Stability Number (RSN) is a complimentary test to the hot filtration stability methods of TSP, TSA, TSE. Using this method, the fuel is mixed with toluene which is aromatic and keeps the asphaltenes in solution. If the sample has poor stability reserve, then asphaltenes will precipitate when Heptane is added- which is naphthenic. As asphaltenes fall out of solution the transmittance through the sample increases resulting in a measure of the separability number.
Separability Number is an excellent accompaniment to the routine hot filtration methods. It can identify potentially troublesome fuels (unstable) even when the HFT method is indicating a low sediment content. Conversely, it may indicate that a high sediment fuel is in fact quite stable and unlikely to form sludge. This information in combination, is extremely useful from an operational perspective, as it will indicate in advance if and what mitigation steps are appropriate.
Note: The full article on ‘How stable is your marine fuel?’ can be viewed here.
Photo credit: VPS
Published: 23 July, 2025